The extent of the asymmetric addition of dialkylzincs to chiral α-siloxyaldehydes is determined by the configuration of the chiral catalyst and not by the chirality of α-siloxyaldehydes, providing either diastereoisomer of mono-protected vicinal diols in high diastereoisomeric excess.
K. Soai, C. Shimada, M. Takeuchi and M. Itabashi, J. Chem. Soc., Chem. Commun., 1994, 567 DOI: 10.1039/C39940000567
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