The first X-ray structural analysis of a carbanion having a carbocation as the counterion, [EtC(CO2Me)2]–C[(NMe2)3]+ is reported, showing unusual hydrogen bonding between the carbanion and the methyl groups of the carbocation.
M. T. Reetz, C. Bingel and K. Harms, J. Chem. Soc., Chem. Commun., 1993, 1558 DOI: 10.1039/C39930001558
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