Issue 20, 1993
From the journal:

Journal of the Chemical Society, Chemical Communications

A volatile mixed-metal yttrium–barium compound: synthesis and molecular structure of bay2[µ-och(cf3)2]4(thd)4(thd = 2,2,6,6-tetramethylheptane-3,5-dionato)

Florence Labrize,   Liliane G. Hubert-Pfalzgraf,   Jean-Claude Daran  and  Sabine Halut  

Abstract

The volatile compound, Y2Ba[OCH(CF3)2]4(thd)4, is obtained by treating a mixed-metal yttrium–barium hexafluoroisopropoxide derivative and yttrium tetramethylheptanedionate Y(thd)3; its structure is based on a central Ba[OCH(CF3)2]42– moiety connected to two Y(thd)2 fragments via the alkoxide ligands; barium–fluorine interactions lead to a twelve-coordinated metal while Y is six-coordinate.

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Article information

DOI
https://doi.org/10.1039/C39930001556
Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 1556-1558

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A volatile mixed-metal yttrium–barium compound: synthesis and molecular structure of bay2[µ-och(cf3)2]4(thd)4(thd = 2,2,6,6-tetramethylheptane-3,5-dionato)

F. Labrize, L. G. Hubert-Pfalzgraf, J. Daran and S. Halut, J. Chem. Soc., Chem. Commun., 1993, 1556 DOI: 10.1039/C39930001556

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