The cyclopentenone 8, synthesised by palladium mediated ring expansion of the chiral vinylcyclobutanols 3 and 4, is converted to the thermodynamically unstable ketone 16 which on methylenation gives (+)-laurene 1.
H. Nemoto, M. Nagamochi and K. Fukumoto, J. Chem. Soc., Chem. Commun., 1992, 1695 DOI: 10.1039/C39920001695
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