By treatment with dihydrosilanes at 150 °C a diruthenium carbonyl complex Ru2(C5H5)2(µ-CO)2(CO)2 is sequentially transformed into a µ-methylene complex Ru2(C5H5)2(µ-CH2)(µ-CO)(CO)2 and a di(µ-methylene) complex Ru2(C5H5)2(µ-CH2)2(CO)2.
M. Akita, T. Oku and Y. Moro-Oka, J. Chem. Soc., Chem. Commun., 1992, 1031 DOI: 10.1039/C39920001031
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