Issue 12, 1992

Novel generation of phenylsulfenium ion and aromatic phenylthiolation. Reactions of hydrazoic acid, alkyl azides and hydroxylamine derivatives with alkyl phenyl sulfides in the presence of both trifluoromethanesulfonic acid and trifluoroacetic acid

Abstract

Reactions of hydrazoic acid and alkyl azides with alkyl phenyl sulfides in the presence of both trifluoromethanesulfonic acid and trifluoroacetic acid gave 4-alkylthiophenyl phenyl sulfides in high yields via a phenylsulfenium ion.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 916-917

Novel generation of phenylsulfenium ion and aromatic phenylthiolation. Reactions of hydrazoic acid, alkyl azides and hydroxylamine derivatives with alkyl phenyl sulfides in the presence of both trifluoromethanesulfonic acid and trifluoroacetic acid

H. Takeuchi, T. Yanase, K. Itou, H. Ōya and T. Adachi, J. Chem. Soc., Chem. Commun., 1992, 916 DOI: 10.1039/C39920000916

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