A novel construction of polyfunctionalised trans-hydroindanes via sulphur-mediated intramolecular double Michael type reaction
Abstract
trans-Hydroindanes possessing an angular methyl group were stereoselectively synthesised via treatment of the four geometrical isomers 1a–1d of 9-rnethoxycarbonyl-4-methyl-1-phenylthionona-1,8-dien-3-one with tert-butyldimethylsilyl trifluoromethanesulphonate in the presence of triethylamine.