Issue 17, 1991

The O-bonded monometallic and O- and C-bonded dimetallic form of N,N-diphenylacetamide enolate with transition metals: X-ray structure of [Ph2N–C(CH2)OZr(η5-C5H5)2(Cl)] and [Ph2N–C{CH2Cr(CO)5}OZr(η5-C5H5)2(Cl)]

Abstract

The N,N-diphenylacetamide enolato anion oxygen bonded to zirconium in [Ph2N–C(CH2)OZr-(η5-C5H5)2(Cl)] has been synthesised, which, when reacted with [Cr(CO)5(thf)], led to the dimetallic form of the amide enolato O-bonded to zirconium and C-bonded to chromium.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 1166-1167

The O-bonded monometallic and O- and C-bonded dimetallic form of N,N-diphenylacetamide enolate with transition metals: X-ray structure of [Ph2N–C(CH2)OZr(η5-C5H5)2(Cl)] and [Ph2N–C{CH2Cr(CO)5}OZr(η5-C5H5)2(Cl)]

P. Veya, C. Floriani, A. Chiesi-Villa and C. Guastini, J. Chem. Soc., Chem. Commun., 1991, 1166 DOI: 10.1039/C39910001166

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