The O-bonded monometallic and O- and C-bonded dimetallic form of N,N-diphenylacetamide enolate with transition metals: X-ray structure of [Ph2N–C(CH2)OZr(η5-C5H5)2(Cl)] and [Ph2N–C{CH2Cr(CO)5}OZr(η5-C5H5)2(Cl)]
Abstract
The N,N-diphenylacetamide enolato anion oxygen bonded to zirconium in [Ph2N–C(CH2)OZr-(η5-C5H5)2(Cl)] has been synthesised, which, when reacted with [Cr(CO)5(thf)], led to the dimetallic form of the amide enolato O-bonded to zirconium and C-bonded to chromium.