Issue 10, 1991

Evidence for an unusual kinetic phenomenon in the metallation of porphyrins

Abstract

Reaction of copper(II) with water soluble porphyrins (H2porph) in the presence of ethylenediamine shows an unusual and so far unreported kinetic phenomenon that can be explained in terms of supramolecular assembly formation apparently involving all solute species as confirmed via light scattering and conductivity measurements.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 731-732

Evidence for an unusual kinetic phenomenon in the metallation of porphyrins

F. González-Vílchez, R. A. Vilaplana and R. F. Pasternack, J. Chem. Soc., Chem. Commun., 1991, 731 DOI: 10.1039/C39910000731

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