N-Sulphinylperfluoroalkanesulphonamides, RfSO2NSO, which are prepared by refluxing of perfluoroalkanesulphonamides with thionyl chloride, react easily with aldehydes, ketones, sulphoxides and phosphorus trichloride oxide yielding a series of new compounds RfSO2N![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
Y (Y = CHAr, CR1R2, SR1R2 and PCl3) with elimination of sulphur dioxide.
S. Zhu and Q. Chen, J. Chem. Soc., Chem. Commun., 1991, 732 DOI: 10.1039/C39910000732
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