The mechanisms of the [(Ph3P)2N][H3Ru4(CO)12]1 catalysed disproportionation and transfer-hydrogenations of cyclohex-2-en-1-one have been shown to involve free radicals; in the latter reaction 1 is converted to other carbonyl species via autocatalysis.
S. Bhaduri, D. Mukesh and K. Sharma, J. Chem. Soc., Chem. Commun., 1990, 1506 DOI: 10.1039/C39900001506
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