Issue 21, 1990

A triangulo-triplatinum cluster with no bridging atom: the structure of [Pt3(2,6-Me2C6H3NC)2(µ-Ph2PCH2PPh2)3]2+

Abstract

The complex cation [Pt3(2,6-Me2C6H3NC)2(µ-dppm)3]2+, dppm = Ph2PCH2PPh2, characterized by X-ray structure analysis, is the first triplatinum cluster which contains no single-atom bridging ligand; it completes a series of clusters based on the equatorial [Pt3(µ-dppm)3] unit in which two axial ligands, L, are present and in which structures with Pt33-L)2, Pt33-L)(L) and Pt3(L)2 units are very close in energy.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1990, 1462-1464

A triangulo-triplatinum cluster with no bridging atom: the structure of [Pt3(2,6-Me2C6H3NC)2(µ-Ph2PCH2PPh2)3]2+

A. M. Bradford, N. C. Payne, R. J. Puddephatt, D. Yang and T. B. Marder, J. Chem. Soc., Chem. Commun., 1990, 1462 DOI: 10.1039/C39900001462

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