Reaction of sodium benzenesulphinate with 1,2-di(4-chlorobenzenesulphonyl)hex-2-en-4-yne affords not only the regiospecific addition of the nucleophile at C(5) but also effects concomitant vinylic and allylic displacements at C(1) and (2).
B. S. Thyagarajan, R. A. Chandler, M. Evans and A. Santillan, J. Chem. Soc., Chem. Commun., 1990, 1464 DOI: 10.1039/C39900001464
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