Labelling experiments showing that 13C2[from Si(13C2H3)4] can be incorporated into the C3 and C4 products from CO–H2 over Rh–CeO2–SiO2 are consistent with the intermediary of surface vinyls, as had been suggested by the analysis of decomposition reactions of model dirhodium complexes.
F. Ma, G. J. Sunley, I. M. Saez and P. M. Maitlis, J. Chem. Soc., Chem. Commun., 1990, 1279 DOI: 10.1039/C39900001279
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