Stannyl-cupration of allenes followed by electrophilic attack gives allyl- and vinylstannanes with a variety of substitution patterns; the regiochemistry of the reaction depends upon the temperature and the nature of the stannyl-cuprate reagent.
A. Barbero, P. Cuadrado, I. Fleming, A. M. González and F. J. Pulido, J. Chem. Soc., Chem. Commun., 1990, 1030 DOI: 10.1039/C39900001030
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