Photolysis of Fe(CO)5 adsorbed on hydrated alumina produced simultaneously hydride species, [HFe3(CO)11]– and [HFe(CO)4]–, and an intermediate species, Fe(CO)4 adsorbed on the basic sites of alumina.
S. Sato and T. Ohmori, J. Chem. Soc., Chem. Commun., 1990, 1032 DOI: 10.1039/C39900001032
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