Issue 19, 1989

A novel macrocycle containing the 4,5-dithio-1,3-dithiole-2-thione unit and a related macrocycle incorporating the tetrathiafulvalene moiety

Abstract

A novel macrocycle (3) incorporating the 4,5-dithio-1,3-dithiole-2-thione unit has been prepared from 2,6-bis(bromomethyl)pyridine and 4,5-bis(benzoylthio)-1,3-dithiole-2-thione: intramolecular triethylphosphite coupling of (3) leads to a novel macrocyclic π-donor (4) incorporating a non-planar tetrathiafulvalene moiety; the crystal structures of (3) and (4) are reported.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1989, 1406-1409

A novel macrocycle containing the 4,5-dithio-1,3-dithiole-2-thione unit and a related macrocycle incorporating the tetrathiafulvalene moiety

B. Girmay, J. D. Kilburn, A. E. Underhill, K. S. Varma, M. B. Hursthouse, M. E. Harman, J. Becher and G. Bojesen, J. Chem. Soc., Chem. Commun., 1989, 1406 DOI: 10.1039/C39890001406

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements