The reaction of [Ti(C5Me5)MeY]2(µ-O)(Y = Me, Cl) and CO gives η2-acetone complexes, which liberate Me2CO upon treatment with oxygen and Me2CHOH upon hydrolysis, and their thermal decomposition proceeds with deoxygenation of the acetone ligand and propene formation; spectroscopic data and labelling experiments are discussed.
J. C. Flores, M. Mena, P. Royo and R. Serrano, J. Chem. Soc., Chem. Commun., 1989, 617 DOI: 10.1039/C39890000617
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