Issue 10, 1989

Macrocyclic tetramanganese(II) complexes with alkoxy and chloro or azido bridges; X-ray crystal structures of [Mn2(HL)(Cl)2]2(ClO4)2·2dmf·H2O and [Mn2(HL)(N3)2]2(ClO4)2·3MeCN (H2L = 1,7,14,20-tetramethyl-2,6,15,19-tetra-aza[7,7](2,6)pyridinophane-4,7-diol; dmf = dimethylformamide)

Abstract

Two tetranuclear MnII complexes are described; complex (1) incorporates both oxygen and chlorine bridging atoms as postulated for the oxygen evolving complex of photosystem II.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1989, 619-620

Macrocyclic tetramanganese(II) complexes with alkoxy and chloro or azido bridges; X-ray crystal structures of [Mn2(HL)(Cl)2]2(ClO4)2·2dmf·H2O and [Mn2(HL)(N3)2]2(ClO4)2·3MeCN (H2L = 1,7,14,20-tetramethyl-2,6,15,19-tetra-aza[7,7](2,6)pyridinophane-4,7-diol; dmf = dimethylformamide)

S. Brooker and V. McKee, J. Chem. Soc., Chem. Commun., 1989, 619 DOI: 10.1039/C39890000619

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