Issue 6, 1989

Stereoselective dioxygenation of a racemic tryptophan derivative catalysed by chiral manganese porphyrins

Abstract

The first asymmetric dioxygenation reactions of the racemic tryptophan derivatives, N-acetyl-L-(+)-[and D-(–)]-tryptophan methyl ester, are reported, in which predominant generation of methyl 2-D-acetoamido-3-(2-formamidobenzoyl)propionate has been acheived in 23.3% enantiometric excess in the cataytic system using the manganese complex of α,α,α,α-tetrakis[O-L(–)-camphanoylamido) phenyl]porphyrin.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1989, 352-354

Stereoselective dioxygenation of a racemic tryptophan derivative catalysed by chiral manganese porphyrins

K. Ohkubo, T. Sagawa, M. Kuwata, T. Hata and H. Ishida, J. Chem. Soc., Chem. Commun., 1989, 352 DOI: 10.1039/C39890000352

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