Natural granaticin (1) has been synthesized by joining the chiral left and right fragments, (5) and (10), and subsequent lactonization of the resulting product (11) and oxidative O-demethylation.
K. Okazaki, K. Nomura and E. Yoshii, J. Chem. Soc., Chem. Commun., 1989, 354 DOI: 10.1039/C39890000354
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