Effects of sodium ions on the molecular dynamics of bis(aza-15-crown-5)thiuram disulphide
Abstract
Oxidative dimerization of sodium (aza-15-crown-5) dithiocarbamate affords bis(aza-15-crown-5)-thiuram disulphide, which exhibits dramatic changes in the dynamic 13C-{1H} n.m.r. spectrum upon addition of sodium ions.