Issue 5, 1988

Thermolysis of [(η3-allyl)PdMe(PPh3)]: an unexpected evolution of ethane gas as a main product

Abstract

The novel title complex thermally decomposes with preferential evolution of ethane rather than but-1-ene, the allylic alkylation product, indicating that the binuclear methyl-bridged intermediate formed by phosphine dissociation predominantly participates in this thermolysis.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1988, 403-404

Thermolysis of [(η3-allyl)PdMe(PPh3)]: an unexpected evolution of ethane gas as a main product

Y. Hayashi, Y. Nakamura and K. Isobe, J. Chem. Soc., Chem. Commun., 1988, 403 DOI: 10.1039/C39880000403

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