The bimetallic cluster [Ru5H(CO)18(µ4-Bi)] has been prepared from the reaction of Bi(NO3)3·5H2O and Na[Ru3H(CO)11] in methanol, and shown by X-ray analysis to be a spiro-cluster containing a ‘Ru2(CO)8’ fragment connected to a ‘Ru3H(CO)10’ fragment by a µ4-bismuth atom with a pseudo-tetrahedral co-ordination geometry.
B. F. G. Johnson, J. Lewis, P. R. Raithby and A. J. Whitton, J. Chem. Soc., Chem. Commun., 1988, 401 DOI: 10.1039/C39880000401
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