Under homogeneous conditions, the silver(I)-catalysed cyclisation of the allenic amine derivatices (3a–c), thogh not (3d), is stereoselective giving cis-2,5-disubstituted pyrrolidines in high yield; cyclisation on (3a), using a heterogeneous silver(I)-catalyst, is nonstereoselective.
R. Kinsman, D. Lathbury, P. Vernon and T. Gallagher, J. Chem. Soc., Chem. Commun., 1987, 243 DOI: 10.1039/C39870000243
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