Issue 3, 1987

Octacarbonyldicobalt induced conversion of 1,2-diaroyldiaziridines into dihydro-oxazoles (oxazolines)

Abstract

1,2-Diaroyldiaziridines react with octacarbonyldicobalt in benzene, at 65–70°C, to give dihydro-oxazoles by an intramolecular displacement-rearrangement reaction; thermal rearrangement of the strained-ring heterocycles affords 4,5-dihydro-oxadiazoles.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 212-213

Octacarbonyldicobalt induced conversion of 1,2-diaroyldiaziridines into dihydro-oxazoles (oxazolines)

D. Roberto and H. Alper, J. Chem. Soc., Chem. Commun., 1987, 212 DOI: 10.1039/C39870000212

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