Issue 21, 1985

Synthesis and solvolysis of a novel cyclic dienynyl trifluoromethanesulphonate

Abstract

Cyclodeca-1,3-dien-5-yn1-yl trifluoromethanesulphonate (2) has been synthesized and solvolysed in different solvent systems to give cyclized aromatic products exclusively, which are formed mainly via an aryl cation (5) intermediate.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1985, 1487-1489

Synthesis and solvolysis of a novel cyclic dienynyl trifluoromethanesulphonate

M. Hanack and R. Rieth, J. Chem. Soc., Chem. Commun., 1985, 1487 DOI: 10.1039/C39850001487

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