Molybdenum-95 n.m.r. spectroscopy as a probe of biological systems: the detection of tetraoxo- and tetrathio-molybdate(VI) bound to bovine serum albumin
Abstract
The feasibility of using 95Mo n.m.r. spectroscopy to monitor the environment of this nucleus in biochemical systems has been established by the observation of the binding of [MoO4]2– and [MoS4]2– to the protein bovine serum albumin.