Issue 9, 1984
From the journal:

Journal of the Chemical Society, Chemical Communications

Laser flash photolysis of hydridotetrakis(diethyl phenylphosphonite)cobalt(I). Direct evidence for the existence of a co-ordinatively unsaturated species

Shigero Oishi,   Keiko Tajime,   Akeri Hosaka  and  Isao Shiojima  

Abstract

A transient species (λmax: 580 nm, ε: 1.7 × 103 dm3 mol–1 cm–1) observed 0.43 µs after nitrogen laser pulse excitation of hydridotetrakis(diethyl phenylphosphonite)cobalt(I) in cyclohexane has been identified as a co-ordinatively unsaturated species, to which diethyl phenylphosphonite and hex-1-ene co-ordinate with second-order rate constants of 1.4 × 108 and 1.1 × 108 dm3 mol–1s–1 respectively.

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Article information

DOI
https://doi.org/10.1039/C39840000607
Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 607-608

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Laser flash photolysis of hydridotetrakis(diethyl phenylphosphonite)cobalt(I). Direct evidence for the existence of a co-ordinatively unsaturated species

S. Oishi, K. Tajime, A. Hosaka and I. Shiojima, J. Chem. Soc., Chem. Commun., 1984, 607 DOI: 10.1039/C39840000607

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