Issue 9, 1984
From the journal:

Journal of the Chemical Society, Chemical Communications

Metal cluster expansion by addition of low-valent group 4B reagents: crystal and molecular structure of [Os3SnH2(CO)10{CH(SiMe3)2}2]; a compound with hydrogen bridging osmium and tin

Christine J. Cardin,   David J. Cardin,   Hans E. Parge  and  John M. Power  

Abstract

Cluster expansion of [Os3H2(CO)10] with [SnR2][R = CH(SiMe3)2] take place in high yield to give [Os3SnH2(CO)10R2], the first closed triosmium–main-group metal cluster to be structurally characterized; a novel feature is the presence of a hydrogen atom bridging the tin atom and one of the osmium atoms.

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Article information

DOI
https://doi.org/10.1039/C39840000609
Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 609-610

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Metal cluster expansion by addition of low-valent group 4B reagents: crystal and molecular structure of [Os3SnH2(CO)10{CH(SiMe3)2}2]; a compound with hydrogen bridging osmium and tin

C. J. Cardin, D. J. Cardin, H. E. Parge and J. M. Power, J. Chem. Soc., Chem. Commun., 1984, 609 DOI: 10.1039/C39840000609

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