Issue 6, 1983

Electrochemical one-electron oxidation of [Ru(NO)Cl5]2–: spectroscopic and magnetic evidence for the (t2g5) ruthenium (III) pentachloronitrosyl complex monoanion [Ru(NO)Cl5]

Abstract

Voltammetric measurements establish a reversible one-electron oxidation for [Ru(NO)Cl5]2– in CH2Cl2; the i.r. and e.s.r. spectra and magnetic properties of the electrogenerated deep green product are consistent with low- spin [Ru(NO)Cl5], and quit different from the properties recently attributed to this anion.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 303-304

Electrochemical one-electron oxidation of [Ru(NO)Cl5]2–: spectroscopic and magnetic evidence for the (t2g5) ruthenium (III) pentachloronitrosyl complex monoanion [Ru(NO)Cl5]

V. T. Coombe, G. A. Heath, T. A. Stephenson and D. A. Tocher, J. Chem. Soc., Chem. Commun., 1983, 303 DOI: 10.1039/C39830000303

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements