Trimethylaluminium methylates the cacodylate anion ([AsMe2O2]–) with the formation of [AsMe4]2[Me2AlO·AlMe3]2, and an X-ray crystal structure has shown the aluminoxane anion to consist of a planar Al2O2 ring with AlMe3 molecules co-ordinated to the oxygen atoms.
J. L. Atwood and M. J. Zaworotko, J. Chem. Soc., Chem. Commun., 1983, 302 DOI: 10.1039/C39830000302
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