Proton-catalysed isomerization of cumulenic amines
Abstract
Cumulenic amines R1CH![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
CC(R3)NR22(R1 and R2H or alkyl, R3H or Me) are converted rapidly at 20 °C into enyne amines R1C![[triple bond, length half m-dash]](https://www.rsc.org/images/entities/char_e007.gif)
C–CHC(R3)NR22 with methanol or water under neutral conditions.
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Article information
- Article type
- Paper
J. Chem. Soc., Chem. Commun., 1983, 79-80
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Proton-catalysed isomerization of cumulenic amines
P. E. van Rijn, W. Klop, H. D. Verkruijsse, P. V. R. Schleyer and L. Brandsma, J. Chem. Soc., Chem. Commun., 1983, 79 DOI: 10.1039/C39830000079
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