Issue 2, 1983
From the journal:

Journal of the Chemical Society, Chemical Communications

E.s.r. evidence for the formation of new vinyl radicals in solution

Toshihiko Ozawa  and  Takao Kwan  

Abstract

The new vinyl radicals HC(SO3–)[double bond, length half m-dash]ĊCMe2OH, HC(SO3–)[double bond, length half m-dash]ĊCH2OH, and HC(SO3–)[double bond, length half m-dash]ĊCH(Me)OH were observed during the reactions of the SO3– radical with the corresponding alkynes 3-methylbut-1-yn-3-ol, prop-2-ynyl alcohol, and but-1-yn-3-ol, respectively, by use of an e.s.r. method coupled with a rapid-mixing flow technique which allows the detection of radicals having life-times of 5–100 ms.

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Article information

DOI
https://doi.org/10.1039/C39830000080
Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 80-81

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E.s.r. evidence for the formation of new vinyl radicals in solution

T. Ozawa and T. Kwan, J. Chem. Soc., Chem. Commun., 1983, 80 DOI: 10.1039/C39830000080

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