Mass–law experiments using added nucleofuge exclude the existence of free sulphur trioxide as an intermediate in the solvolysis of isoquinoline N-sulphonate in 80% acetonitrile solution (v/v) containing 4.4M-water.
A. Hopkins and A. Williams, J. Chem. Soc., Chem. Commun., 1983, 37 DOI: 10.1039/C39830000037
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