Potassium ions in KC36 can react with the 3-dimensional cryptand ‘K222’(4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo[8.8.8]hexacosane) to yield a first-stage intercalation compound with an interlayer spacing di= 15.5 Å in which the K+ ions are probably within the macroheterobicyclic cage.
R. Setton, F. Béguin, L. Facchini, M. F. Quinton, A. P. Legrand, B. Ruisinger and H. P. Boehm, J. Chem. Soc., Chem. Commun., 1983, 36 DOI: 10.1039/C39830000036
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