A detailed e.s.r. study of low-spin cobalt(II) porphyrins with formula [CoLL′(O2)] has shown that the spin-Hamiltonian parameters are hardly sensitive to changes in L (meso-substituted porphyrin) and L′(nitrogenous base). Only where L is protoporphyrin IX dimethyl ester are clearly discerned effects observed upon changing substituents on L′.
I. M. Ruzic, T. D. Smith and J. R. Pilbrow, J. Chem. Soc., Dalton Trans., 1981, 2365 DOI: 10.1039/DT9810002365
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