Issue 12, 1981
From the journal:

Journal of the Chemical Society, Dalton Transactions

Mechanism of water substitution in the trigonal-bipyramidal complex [Cu(tren)(OH2)]2+(tren = 2,2′,2″-triaminotriethylamine): evidence for an associative mechanism

George R. Cayley,   Iain D. Kelly,   Peter F. Knowles  and  Kapil D. S. Yadav  

Abstract

The mechanism of substitution of water in the title complex by a series of pyridine derivatives has been studied using temperature-jump relaxation spectrophotometry. The dependence of kf and kb on the nature of the ligand and the values of the activation parameters offer strong support for an associative mechanism.

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Article information

DOI
https://doi.org/10.1039/DT9810002370
Article type
Paper

J. Chem. Soc., Dalton Trans., 1981, 2370-2372

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Mechanism of water substitution in the trigonal-bipyramidal complex [Cu(tren)(OH2)]2+(tren = 2,2′,2″-triaminotriethylamine): evidence for an associative mechanism

G. R. Cayley, I. D. Kelly, P. F. Knowles and K. D. S. Yadav, J. Chem. Soc., Dalton Trans., 1981, 2370 DOI: 10.1039/DT9810002370

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