The reaction of dioxygen with αβγδ-tetraphenyl-porphinatochromium (II) in toluene proceeds in two stages; a µ-oxo-chromium(III) intermediate is formed initially and this then further reacts with dioxygen to give the title complex, the structure of which has been determined by X-ray crystallography.
J. R. Budge, B. M. K. Gatehouse, M. C. Nesbit and B. O. West, J. Chem. Soc., Chem. Commun., 1981, 370 DOI: 10.1039/C39810000370
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