Analysis of variable temperature circular dichroism spectra of (+)-(5R)-t-butylcyclohexa-1,3-diene gave a conformational energy of 1·7 kJ/mol, indicating that where 1,3-diaxial interactions are minimised, the equatorial configuration is only slightly favoured over the axial.
D. A. Lightner and J. L. Chappuis, J. Chem. Soc., Chem. Commun., 1981, 372 DOI: 10.1039/C39810000372
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