Hydrogen atoms generated by γ-radiolysis of aqueous sulphuric acid matrices at 77 K add to Pt(CN)4,2– ions to give [H–Pt(CN)4]2– ions, the unpaired electron being in a σ* orbital confined to hydrogen (ca. 35%) and platinum; electron addition followed by proton addition in methanol matrices gave the same complex.
M. C. R. Symons, M. M. Aly and J. L. Wyatt, J. Chem. Soc., Chem. Commun., 1981, 176 DOI: 10.1039/C39810000176
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