14β-Hydroxywithanone (1), the first example of a 14β-substitution among withanolides, was isolated with Withania somnifera and its structure established by X-Ray analysis.
S. S. Nittala, F. Frolow and D. Lavie, J. Chem. Soc., Chem. Commun., 1981, 178 DOI: 10.1039/C39810000178
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