Issue 23, 1980

Quinone-capped metalloporphyrins: synthesis and co-ordination chemistry

Abstract

Compounds in the title series have been synthesised by capping mesoporphyrin-II with protected hydroquinone derivatives, deprotection, and oxidation, followed by magnesium insertion; 1H n.m.r. spectroscopy demonstrates that the metal ion is 5-co-ordinate, bound intramolecularly to a quinone carbonyl oxygen, and can accept a sixth ligand from the unhindered side.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1980, 1129-1131

Quinone-capped metalloporphyrins: synthesis and co-ordination chemistry

K. N. Ganesh and J. K. M. Sanders, J. Chem. Soc., Chem. Commun., 1980, 1129 DOI: 10.1039/C39800001129

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