The iron(I) complex [Fe(CO)3(PPh3)2]+ undergoes novel radical–radical coupling and redox reactions, with paramagnetic (NO, NO2, etc.) and diamagnetic ([S2CNR2]– S2[graphic omitted]R3, etc.) ligands, respectively, to give iron(II) carbonyl derivatives such as [Fe(NO2)(CO)3(PPh3)2]+ and [Fe(CO)2(PPh3)2(S2CPPh3)]2+.
P. K. Baker, K. Broadley and N. G. Connelly, J. Chem. Soc., Chem. Commun., 1980, 775 DOI: 10.1039/C39800000775
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