The nitroxides formed by radical addition to the spin trap 5,5-dimethylpyrroline N-oxide are extensively dimerized in aqueous solution and this constitutes a serious limitation to the use of the trap in quantitative studies of radical production.
A. T. Bullock, D. L. Gavin and M. D. Ingram, J. Chem. Soc., Chem. Commun., 1980, 327 DOI: 10.1039/C39800000327
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