SCHEDULED MAINTENANCE:
The magnesium complex (1) has been found to undergo fixation of carbon dioxide and the resulting 1-carboxylato-complex (2) transfers the carboxylato group to active methylene compounds (3) including acetophenone, benzylideneacetone, β-ionone, and S-benzyl thioacetate, under mild conditions.
N. Matsumura, Y. Sakaguchi, T. Ohba and H. Inoue, J. Chem. Soc., Chem. Commun., 1980, 326 DOI: 10.1039/C39800000326
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