Kinetic hydrogen isotope effects on the decomposition of nitramide catalysed by a series of phosphonate anions and the 2,4,6-trichlorophenoxide ion were found to be small (kH/kDca. 2–3) with no sign of a maximum value of pKa(catalyst conjugate acid)ca. 6, in disagreement with a previously reported claim but consistent with the expected pKa of the reactive form of the substrate.
A. J. Kresge, Y. C. Tang, A. Awwal and D. P. Onwood, J. Chem. Soc., Chem. Commun., 1980, 310 DOI: 10.1039/C39800000310
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