Solvent effects on equilibria between configurational isomers of fixed conformation may be studied quantitatively by gas-chromatographic analysis of the head-space above solutions containing a standard ratio of the isomers; as an example, solvent effects on the cis- and trans-4-t-butylcyclohexanol equilibrium are reported.
M. H. Abraham, A. Nasehzadeh, M. J. Cook and F. Kaberia, J. Chem. Soc., Chem. Commun., 1980, 312 DOI: 10.1039/C39800000312
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