Issue 20, 1979

Characterisation of an osmium cluster carbonyl containing a weakly co-ordinated amine ligand; X-ray crystal and molecular structure of [Os3(CO)9(NO)2(NMe3)]

Abstract

The X-ray structure of the first trialkylamine metal cluster, [Os3(CO)9(NO)2(NMe3)], has been determined; the large steric requirements of the trialkylamine is reflected in the long Os–N distance of the co-ordinated group.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1979, 916-917

Characterisation of an osmium cluster carbonyl containing a weakly co-ordinated amine ligand; X-ray crystal and molecular structure of [Os3(CO)9(NO)2(NMe3)]

B. F. G. Johnson, J. Lewis, P. R. Raithby and C. Zuccaro, J. Chem. Soc., Chem. Commun., 1979, 916 DOI: 10.1039/C39790000916

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