The cycloaddition of azodibenzoyl to a selection of monomers with electron-rich vinyl groups has been shown to compete with its efficient radical-induced decomposition when it is present in systems in which the polymerization of the monomers by a free radical mechanisms is initiated.
F. Bassam and R. G. Jones, J. Chem. Soc., Chem. Commun., 1979, 917 DOI: 10.1039/C39790000917
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